TSPC 66_a_lob

66_a_lob_j01
The principal difficulty encountered by the author, in determining partial molal free energies by solid electrolyte cells of very stable oxides such as UO<bsub>2<ast><bsub>, MnO etc was vapour phase transfer of oxygen by carbonaceous impurities in the blanket gas.

arc(r_0066_0001__The_r_0066_0003__difficulty, r_0066_0002__principal, attrib5).
arc(r_0066_0004__encountered, r_0066_0001__The_r_0066_0003__difficulty, arg1).
arc(r_0066_0004__encountered, r_0066_0006__the_r_0066_0007__author, arg0).
arc(r_0066_0010__determining, r_0066_0014__energies, arg1).
arc(r_0066_0010__determining, r_0066_0018__cells, r_0066_0015__by_nim44).
arc(r_0066_0010__determining, z_000_66_a_lob_j01_26, arg0).
arc(r_0066_0014__energies, r_0066_0011__partial, attrib30).
arc(r_0066_0014__energies, r_0066_0012__molal, attrib33).
arc(r_0066_0014__energies, r_0066_0013__free, attrib36).
arc(r_0066_0018__cells, r_0066_0016__solid, attrib45).
arc(r_0066_0018__cells, r_0066_0017__electrolyte, attrib48).
arc(r_0066_0018__cells, r_0066_0022__oxides, r_0066_0019__of).
arc(r_0066_0021__stable, r_0066_0020__very, qual58).
arc(r_0066_0022__oxides, r_0066_0021__stable, attrib57).
arc(r_0066_0022__oxides, z_000_66_a_lob_j01_69, r_0066_0023__such_as).
arc(r_0066_0026__MnO, r_0066_0027__etc, qual79).
arc(r_0066_0028__was, r_0066_0001__The_r_0066_0003__difficulty, arg0).
arc(r_0066_0028__was, r_0066_0010__determining, r_0066_0009__in_nim26).
arc(r_0066_0028__was, r_0066_0029__vapour_r_0066_0030__phase_r_0066_0031__transfer, prd).
arc(r_0066_0029__vapour_r_0066_0030__phase_r_0066_0031__transfer, r_0066_0033__oxygen, r_0066_0032__of).
arc(r_0066_0029__vapour_r_0066_0030__phase_r_0066_0031__transfer, r_0066_0036__impurities, r_0066_0034__by).
arc(r_0066_0036__impurities, r_0066_0035__carbonaceous, attrib101).
arc(r_0066_0036__impurities, r_0066_0038__the_r_0066_0039__blanket_r_0066_0040__gas, r_0066_0037__in).
arc(z_000_66_a_lob_j01_69, r_0066_0024__UO_bsub_2_ast__bsub_, conj1).
arc(z_000_66_a_lob_j01_69, r_0066_0026__MnO, conj2).

fof(formula,axiom,
    ? [R_0066_0002__PRINCIPAL,R_0066_0001__THE_R_0066_0003__DIFFICULTY,R_0066_0006__THE_R_0066_0007__AUTHOR,R_0066_0004__ENCOUNTERED,R_0066_0011__PARTIAL,R_0066_0012__MOLAL,R_0066_0013__FREE,R_0066_0014__ENERGIES,R_0066_0016__SOLID,R_0066_0017__ELECTROLYTE,R_0066_0020__VERY,R_0066_0021__STABLE,R_0066_0024__UO_BSUB_2_AST__BSUB_,R_0066_0027__ETC,R_0066_0026__MNO,Z_000_66_A_LOB_J01_69,R_0066_0022__OXIDES,R_0066_0018__CELLS,Z_000_66_A_LOB_J01_26,R_0066_0010__DETERMINING,R_0066_0033__OXYGEN,R_0066_0035__CARBONACEOUS,R_0066_0038__THE_R_0066_0039__BLANKET_R_0066_0040__GAS,R_0066_0036__IMPURITIES,R_0066_0029__VAPOUR_R_0066_0030__PHASE_R_0066_0031__TRANSFER,R_0066_0028__WAS] :
      ( r_0066_0002__principal(R_0066_0002__PRINCIPAL)
      & r_0066_0006__the_r_0066_0007__author(R_0066_0006__THE_R_0066_0007__AUTHOR)
      & r_0066_0011__partial(R_0066_0011__PARTIAL)
      & r_0066_0012__molal(R_0066_0012__MOLAL)
      & r_0066_0013__free(R_0066_0013__FREE)
      & r_0066_0016__solid(R_0066_0016__SOLID)
      & r_0066_0017__electrolyte(R_0066_0017__ELECTROLYTE)
      & r_0066_0020__very(R_0066_0020__VERY)
      & r_0066_0024__UO_bsub_2_ast__bsub_(R_0066_0024__UO_BSUB_2_AST__BSUB_)
      & r_0066_0027__etc(R_0066_0027__ETC)
      & r_0066_0033__oxygen(R_0066_0033__OXYGEN)
      & r_0066_0035__carbonaceous(R_0066_0035__CARBONACEOUS)
      & r_0066_0038__the_r_0066_0039__blanket_r_0066_0040__gas(R_0066_0038__THE_R_0066_0039__BLANKET_R_0066_0040__GAS)
      & z_000_66_a_lob_j01_26(Z_000_66_A_LOB_J01_26)
      & r_0066_0028__was(R_0066_0028__WAS)
      & has_prd(R_0066_0028__WAS,R_0066_0029__VAPOUR_R_0066_0030__PHASE_R_0066_0031__TRANSFER)
      & r_0066_0029__vapour_r_0066_0030__phase_r_0066_0031__transfer(R_0066_0029__VAPOUR_R_0066_0030__PHASE_R_0066_0031__TRANSFER)
      & has_r_0066_0034__by(R_0066_0029__VAPOUR_R_0066_0030__PHASE_R_0066_0031__TRANSFER,R_0066_0036__IMPURITIES)
      & r_0066_0036__impurities(R_0066_0036__IMPURITIES)
      & has_r_0066_0037__in(R_0066_0036__IMPURITIES,R_0066_0038__THE_R_0066_0039__BLANKET_R_0066_0040__GAS)
      & has_attrib101(R_0066_0036__IMPURITIES,R_0066_0035__CARBONACEOUS)
      & has_r_0066_0032__of(R_0066_0029__VAPOUR_R_0066_0030__PHASE_R_0066_0031__TRANSFER,R_0066_0033__OXYGEN)
      & has_r_0066_0009__in_nim26(R_0066_0028__WAS,R_0066_0010__DETERMINING)
      & r_0066_0010__determining(R_0066_0010__DETERMINING)
      & has_arg0(R_0066_0010__DETERMINING,Z_000_66_A_LOB_J01_26)
      & has_r_0066_0015__by_nim44(R_0066_0010__DETERMINING,R_0066_0018__CELLS)
      & r_0066_0018__cells(R_0066_0018__CELLS)
      & has_r_0066_0019__of(R_0066_0018__CELLS,R_0066_0022__OXIDES)
      & r_0066_0022__oxides(R_0066_0022__OXIDES)
      & has_r_0066_0023__such_as(R_0066_0022__OXIDES,Z_000_66_A_LOB_J01_69)
      & z_000_66_a_lob_j01_69(Z_000_66_A_LOB_J01_69)
      & has_conj2(Z_000_66_A_LOB_J01_69,R_0066_0026__MNO)
      & r_0066_0026__MnO(R_0066_0026__MNO)
      & has_qual79(R_0066_0026__MNO,R_0066_0027__ETC)
      & has_conj1(Z_000_66_A_LOB_J01_69,R_0066_0024__UO_BSUB_2_AST__BSUB_)
      & has_attrib57(R_0066_0022__OXIDES,R_0066_0021__STABLE)
      & r_0066_0021__stable(R_0066_0021__STABLE)
      & has_qual58(R_0066_0021__STABLE,R_0066_0020__VERY)
      & has_attrib48(R_0066_0018__CELLS,R_0066_0017__ELECTROLYTE)
      & has_attrib45(R_0066_0018__CELLS,R_0066_0016__SOLID)
      & has_arg1(R_0066_0010__DETERMINING,R_0066_0014__ENERGIES)
      & r_0066_0014__energies(R_0066_0014__ENERGIES)
      & has_attrib36(R_0066_0014__ENERGIES,R_0066_0013__FREE)
      & has_attrib33(R_0066_0014__ENERGIES,R_0066_0012__MOLAL)
      & has_attrib30(R_0066_0014__ENERGIES,R_0066_0011__PARTIAL)
      & has_arg0(R_0066_0028__WAS,R_0066_0001__THE_R_0066_0003__DIFFICULTY)
      & r_0066_0001__The_r_0066_0003__difficulty(R_0066_0001__THE_R_0066_0003__DIFFICULTY)
      & has_attrib5(R_0066_0001__THE_R_0066_0003__DIFFICULTY,R_0066_0002__PRINCIPAL)
      & r_0066_0004__encountered(R_0066_0004__ENCOUNTERED)
      & has_arg0(R_0066_0004__ENCOUNTERED,R_0066_0006__THE_R_0066_0007__AUTHOR)
      & has_arg1(R_0066_0004__ENCOUNTERED,R_0066_0001__THE_R_0066_0003__DIFFICULTY) ) ).

( (IP-MAT (NP-SBJ (D The;{the})
                  (ADJP (ADJ principal;{principal}))
                  (N difficulty;{difficulty})
                  (IP-PPL (VVN;__ encountered;{encounter})
                          (PP-LGS (P-ROLE;_lgs_ by;{by})
                                  (NP (D the;{the})
                                      (N author;{author})))))
          (PUNC ,)
          (PP-NIM (P-ROLE in;{in})
                  (IP-PPL (VAG;__ determining;{determine})
                          (NP-OB1 (ADJP (ADJ partial;{partial}))
                                  (ADJP (ADJ molal;{molal}))
                                  (ADJP (ADJ free;{free}))
                                  (NS energies;{energy}))
                          (PP-NIM (P-ROLE by;{by})
                                  (NP (ADJP (ADJ solid;{solid}))
                                      (ADJP (ADJ electrolyte;{electrolyte}))
                                      (NS cells;{cell})
                                      (PP (P-ROLE of;{of})
                                          (NP (ADJP (ADVP (ADV very;{very}))
                                                    (ADJ stable;{stable}))
                                              (NS oxides;{oxide})
                                              (PP (P-ROLE such_as;{such_as})
                                                  (NP (NLYR (NLYR (NPR UO<bsub>2<ast><bsub>;{UO<bsub>2<ast><bsub>}))
                                                            (PUNC ,)
                                                            (CONJP (NLYR (NPR MnO;{MnO})
                                                                         (ADVP (ADV etc;{etc})))))))))))))
          (BED;_Ln_ was;{be})
          (NP-PRD (N vapour;{vapour})
                  (N phase;{phase})
                  (N transfer;{transfer})
                  (PP (P-ROLE of;{of})
                      (NP (N oxygen;{oxygen})))
                  (PP (P-ROLE by;{by})
                      (NP (ADJP (ADJ carbonaceous;{carbonaceous}))
                          (NS impurities;{impurity})
                          (PP (P-ROLE in;{in})
                              (NP (D the;{the})
                                  (N blanket;{blanket})
                                  (N gas;{gas}))))))
          (PUNC .))
  (ID 66_a_lob_j01))